Preheat oven to 425 degrees. NOTE that you will turn the heat down to 350 degrees after the first 10 minutes. Generously grease a bundt pan.
Zest and juice both lemons. Set aside a pinch or two of the zest and 2 tablespoons of the juice for the glaze and garnish. The remainder of both will be used in the batter.
In a small bowl, mix gluten free flour, baking powder, baking soda and salt. Set aside.
In a large bowl, mix the softened butter and sugar with a hand mixer.
Add the following one at a time, mixing between each to incorporate well: eggs, sour cream, lemon juice, and limoncello. Finally stir in the lemon zest just until combined.
Add the flour mixture and combine well.
Pour the batter into a well greased bundt pan and smooth out the top with the back of your spatula.
Bake for 10 minutes at 425 degrees, then turn the heat to 350 and allow to continue baking for another 15-20 minutes. The top should be browned slightly and the center shouldn't jiggle at all. Watch it like a hawk in the last 5-10 minutes of baking for doneness. Don't let it over bake or wait for a dry toothpick test, it will be over baked if you wait that long.